Cement and emulsified asphalt within the cement asphalt emulsion mixture would experienced interactions,which created more complex air void microstructure compared with normal hot mix asphalt. The influence on air void distribution and air void features from emulsion and cement content were studied by computed tomography, air void structure of micro-scale were further researched by scanning electron microscope. The results of the study showed that the air void size, total air void area and average single air void area of cement asphalt emulsion mixture specimens section was decreased with the increase of emulsion content; CT visible air void of mixtures and the ratio of big air void was increased observably when the cement content was more than 3%. Internal air void structure of cement asphalt emulsion mixtures maybe looser than traditional hot mix asphalt for the interaction of cement and emulsion asphalt.