含水乙醇汽油简化化学反应动力学模型
CSTR:
作者:
作者单位:

同济大学,同济大学,同济大学,同济大学

中图分类号:

TK411+.2

基金项目:

上海市自然科学基金资助项目(16ZR1438500);内燃机燃烧学国家重点实验室开放研究课题资助项目(K2016-04);中央高校基本科研业务费专项资金资助.


Reduced Chemical Reaction Kinetic Model of Hydrous Ethanolgasoline Fuel
Author:
  • 摘要
  • | |
  • 访问统计
  • |
  • 参考文献 [29]
  • |
  • 相似文献 [20]
  • |
  • 引证文献
  • | |
  • 文章评论
    摘要:

    引入“半解耦”方法,以H2/CO/C1小分子机理为“内核”,耦合乙醇氧化骨架机理和汽油表征燃料的甲苯参比燃料(TRF)机理,构建乙醇汽油混合燃料的简化化学反应动力学模型.利用CHEMKIN软件进行数值模拟,通过相关实验对该模型进行验证.进一步分析水的影响,构建了含水乙醇汽油简化化学反应动力学模型.与乙醇汽油着火特性实验数据进行对比,验证了该简化机理的合理性.

    Abstract:

    In this paper, the idea of ‘semidecoupling’ is introduced to construct an ethanolgasoline chemical reaction model, which uses the small molecule mechanism of H2/CO/C1 as the ‘core’ with coupling the ethanol skeleton oxidation mechanism and the gasoline toluene reference fuel(TRF) mechanism. By comparing with experimental results available in published literature, the numerical simulation results calculated by CHEMIKIN software can accurately reflect the combustion characteristics of ethanolgasoline fuel. Furthermore, based on the sensitivity analysis of H2O, a hydrous ethanolgasoline reduced chemical kinetic model is established through integrating the chemical reactions of H2O. And the reduced model is verified by the experimental results of ethanolgasoline fuel ignition characteristics.

    参考文献
    姜芹,孙亚琴,滕虎,等. 纤维素燃料乙醇技术经济分析[J]. 过程工程学报,2012,12(1):97-104.
    JIANG Qin, SUN Yaqin, TENG Hu, et al. Techno-economic Analysis of Cellulosic Ethanol[J]. The Chinese Journal of Process Engineering, 2012, 12(1):97-104.
    陈振斌,倪计民,张惜辉,等. 乙醇-丁醇-柴油混合燃料的车辆排放性和经济性[J]. 农业工程学报, 2012, 28(7):62-66.
    CHEN Zhenbin, NI Jimin, ZHANG Xihui, et al. Vehicle emission and fuel consumption of diesel vehicles fueled with ethanol-butanol-diesel blends[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2012, 28(7): 62-66.
    刘耀东.基础燃料(PRF)及汽油表征燃料(TRF)化学反应动力学骨架模型的研究[D].大连:大连理工大学,2013.
    LIU Yaodong. Research on the development of skeletal chemical kinetic models for primary Reference fuel and gasoline surrogate fuel(TRF)[D]. Dalian: Dalian University of Technology, 2013. (in Chinese with English abstract)
    Marinov, N. M. A detailed chemical kinetic model for high temperature ethanol oxidation[J]. International Journal of Chemical Kinetics, 1999, 31(3): 183-220.
    Zhen X, Wang Y, Liu D. An overview of the chemical reaction mechanisms for gasoline surrogate fuels[J]. Applied Thermal Engineering, 2017, 124.
    Halstead M P, Kirsch L J, Quinn C P. The autoignition of hydrocarbon fuels at high temperatures and pressures—Fitting of a mathematical model[J]. Combustion Flame, 1977, 30(77):45-60.
    Curran H J, Pitz W J, Westbrook C K, et al. Oxidation of automotive primary Reference fuels at elevated pressures[J]. Symposium on Combustion, 1998, 27(1):379-387.Mehl M, Pitz W J, Westbrook C K, et al. Kinetic modeling of gasoline surrogate components and mixtures under engine conditions[J]. Proceedings of the Combustion Institute, 2011, 33(1):193-200.
    Liu Y D, Jia M, Xie M Z, et al. Development of a New Skeletal Chemical Kinetic Model of Toluene Reference Fuel with Application to Gasoline Surrogate Fuels for Computational Fluid Dynamics Engine Simulation[J]. Energy Fuels, 2013, 27(8):4899-4909.
    Metcalfe W K, Burke S M, Ahmed S S, et al. A Hierarchical and Comparative Kinetic Modeling Study of C1?C2, Hydrocarbon and Oxygenated Fuels[J]. International Journal of Chemical Kinetics, 2013, 45(10):638–675.
    Mittal G, Burke S M, Davies V A, et al. Autoignition of ethanol in a rapid compression machine[J]. Combustion Flame, 2014, 161(5):1164-1171.
    Klippenstein S J, Harding L B, Davis M J, et al. Uncertainty driven theoretical kinetics studies for CH 3 OH ignition: HO 2 +CH 3 OH and O 2 +CH 3 OH[J]. Proceedings of the Combustion Institute, 2011, 33(1):351-357.
    苏万华,赵华,王建昕,等. 均质压燃低温燃烧发动机理论与技术[M]. 科学出版社, 2010.
    SU Wanhua, ZHAO Hua, WANG Jianxin, et al. Engine Theory and Technology of Homogeneous Charge Compression Combustion and Low Temperature Combustion[M]. Science Press, 2010. (in Chinese with English abstract)
    Cancino L R, Fikri M, Oliveira A A M, et al. Measurement and Chemical Kinetics Modeling of Shock-Induced Ignition of Ethanol?Air Mixtures[J]. Energy Fuels, 2010, 24(5):2830-2840.
    Broustail G, Seers P, Halter F, et al. Experimental determination of laminar burning velocity for butanol and ethanol iso-octane blends[J]. Fuel, 2011, 90(1):1-6.
    暴秀超, 刘福水.氢气/空气混合气层流燃烧速度的实验测量与模拟计算[J].燃烧科学与技术, 2011, 17(5):407-413. (in Chinese with English abstract)
    BAO Xiuchao, LIU Fushui. Measurement and Calculation of Burning Velocity of Hydrogen-Air Laminar Premixed Flames[J]. Journal of Combustion Science and Technology, 2011, 17(5):407-413.
    Fikri M, Herzler J, Starke R, et al. Autoignition of gasoline surrogates mixtures at intermediate temperatures and high pressures[J]. Combustion Flame, 2008, 152(1–2):276-281.
    Cancino L R, Fikri M, Oliveira A A M, et al. Ignition delay times of ethanol-containing multi-component gasoline surrogates: Shock-tube experiments and detailed modeling[J]. Fuel, 2011, 90(3):1238-1244.
    Nanthon, I. D. H. Measuring Laminar Burning Velocities using Constant Volume Combustion Vessel Techniques. Ph.D. Thesis, University of Oxford, 2014.
    Lipzig, J P,Nilsson, E J K,Goey, L. Laminar burning velocities of n -heptane, iso-octane, ethanol and their binary and tertiary mixtures[J]. Fuel, 2011, 90:2773-2781.
    Dirrenberger P, Glaude P A, Bounaceur R, et al. Laminar burning velocity of gasolines with addition of ethanol[J]. Fuel, 2014, 115(1):162-169.
    Jerzembeck S, Glawe C, Peters N. Development and Experimental Evaluation of a High Temperature Mechanism for blended N-Heptane-Isooctane-Ethanol-Air-Mixtures and Gasoline-Ethanol-Air-Mixtures[C]// Recent Advances in Energy and Environment: Iasme/wseas International Conference on Energy and Environment. 2009.
    Liang J, Li G, Zhang Z, et al. Experimental and Numerical Studies on Laminar Premixed Flames of Ethanol–Water–Air Mixtures[J]. Energy Fuels, 2012, 28(7):4754-4761.
    张韦,舒歌群,陈朝辉,等. 柴油机燃用水乳化柴油着火时刻的化学动力学特性[J]. 农业工程学报,2012,28(13):59-66.
    ZHANG Wei, SHU Gequn, CHEN Chaohui, et al. Chemical kinetics of ignition timing of diesel engine fueled with water emulsion diesel[J]. Transactions of the Chinese Society of Agricultural Engineering, 2012, 28(13): 59-66.
    网友评论
    网友评论
    分享到微博
    发 布
引用本文

石秀勇,康杨,罗亨波,倪计民.含水乙醇汽油简化化学反应动力学模型[J].同济大学学报(自然科学版),2018,46(11):1528~1535

复制
分享
文章指标
  • 点击次数:1344
  • 下载次数: 751
  • HTML阅读次数: 632
  • 引用次数: 0
历史
  • 收稿日期:2018-04-24
  • 最后修改日期:2018-09-12
  • 录用日期:2018-07-30
  • 在线发布日期: 2018-11-29
文章二维码