Ozonation of Aqueous Reactive Black 5 Catalyzed by Modified PyC
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    Abstract:

    Pyrite Cinder(PyC)supported Ce by optimized incipient wetness impregnation was prepared to enhance the catalytic activity of PyC in ozonation. TOC removal efficiency of O3/Ce PyC was kept at about 80 % in the pH range of 3 to 10 in the degradation of aqueous Reactive Black 5(RB5)which was quiet different from the case of traditional ozonation. The kinetic analysis showed that the TOC removal rate constant of O3/Ce PyC was 7.22 times higher than that of O3 alone in the degradation of RB5. Moreover, the fact that more than 75 % of TOC removal efficiency while the catalyst was reused for the third time indicated stable catalytic activity of Ce PyC. Surface hydroxyl groups were the key to catalytic activity of PyC while supported Ce enhanced its catalytic activity for its effectiveness in decomposing O3 into HO·. Ce PyC showed its potential application value in wastewater treatment considering the low cost.

    Reference
    [1] Wu J, Wang T, Ozonation of aqueous azo dye in a semi-batch reactor, Water Research, 2001, 35: 1093–1099.
    [2] Gao M, Zeng Z, Sun B, Zou H, Chen J, Shao L, Ozonation of azo dye Acid Red14 in a microporous tube-in-tube microchannel reactor: decolorization and mechanism, Chemosphere, 2012, 89: 190–197.
    [3] Moussavi G, Mahmoudi M, Degradation and biodegradability improvement of the reactive red 198 azo dye using catalytic ozonation with MgO nanocrystals, Chemical Engineering Journal, 2009, 152: 1–7.
    [4] Guzman-Perez CA, Soltan J and Robertson J, Kinetics of catalytic ozonation of atrazine in the presence of activated carbon, Separation and Purification Technology, 2011, 79: 8–14.
    [5] Beltrán FJ, Rivas FJ, Iron type catalysts for the ozonation of oxalic acid in water, Water Research, 2005, 39: 3553–3564.
    [6] Zhang T, Li WW, and Croué J, Catalytic Ozonation of Oxalate with a Cerium Supported Palladium Oxide: An Efficient Degradation Not Relying on Hydroxyl Radical Oxidation, Environmental Science and Technology, 2011, 45: 9339–9346.
    [7] Sui MH, Liu J and Sheng L, Mesoporous material supported manganese oxides (MnOx/MCM-41) catalytic ozonation of nitrobenzene in water, Applied Catalysis B: Environmental, 2011, 106: 195– 203.
    [8] Zhao L, Ma J and Sun ZZ, Mechanism of heterogeneous catalytic ozonation of nitrobenzene in aqueous solution with modified ceramic honeycomb, Applied Catalysis B: Environmental, 2009, 89: 326–334.
    [9] Stumm W, Morgan JJ. Aquatic chemistry: chemical equilibria and rates in natural waters, 3rd ed. Wiley, New York, 1981. pp. 516–608.
    [10] Beltran FR, Monterodeespinosa F, A TiO2/Al2O3 catalyst to improve the ozonation of oxalic acid in water, Applied Catalysis B: Environmental, 2004, 47: 101–109.
    [11] Carla AO, José JM, Manuel FR, André MD, Marco AF, Ceria and cerium-based mixed oxides as ozonation catalyst, Chemical Engineering Journal, 2012, 200-202: 499-505.
    [12] Stumm W. Chemistry of the solid-water interface: processes at the mineral-water and particle-water interface in natural systems, John Wiley and Sons, New York, 1992.
    [13] Martins RC, Quinta-Ferreira RM, Catalytic ozonation of phenolic acids over a Mn–Ce–O catalyst, Applied Catalysis B: Environmental 2009, 90: 268–277.
    [14] Liu XY, Zhou ZM, Jing GH, Fang JH, Catalytic ozonation of Acid Red B in aqueous solution over a Fe–Cu–O catalyst, Separation and Purification Technology, 2013, 115: 129–135.
    [15] Erol F, ?zbelge TA, Catalytic ozonation with non-polar bonded alumina phases for treatment of aqueous dye solutions in a semi-batch reactor, Chemical Engineering Journal, 2008, 139: 272–283.
    [16] Hoigné J, Bader H, Rate constants of reactions of ozone with organic and inorganic compounds in water—II: dissociating organic compounds, Water Research, 1983, 17: 185–194.
    [17] Getoff N, Schw?rer F and Markovic VM, Hydroxyl radical induced decomposition of aliphatic acids in oxygenated and deoxygenated aqueous solutions, Journal of Physical Chemistry, 1971, 75: 749–755.
    [18] Joseph Y, Ranke W and Weiss W, Water on FeO (111) and Fe3O4 (111): Adsorption behavior on different surface terminations, Journal of Physical Chemistry B, 2000, 104: 3224–3236.
    [19] Zhang T and Ma J, Catalytic ozonation of trace nitrobenzene in water with synthetic goethite, Journal of Molecular Catalysis A: Chemical, 2008, 279: 82–89.
    [20] 马军,张涛,陈忠林,隋铭皓,李学艳,水中羟基氧化铁催化臭氧分解和氧化痕量硝基苯的机理探讨,环境科学,2005,26:78-82. Ma J, Zhang T, Chen ZL, Sui MH, Li XY, The mechanism of ozone decomposition and trace nitrobenzene ozonation catalyzed by ferric hydroxide, Environmental Science-China, 2005, 26: 78-82.
    [21] Gunten UV, Ozonation of drinking water: Part I. Oxidation kinetics and product formation, Water Research, 2003, 37: 1443–1467.
    [22] Alexandra G, Joaquí S, Enrique VR, Juan CS, José JM, Antonio SE, Manuel FR, Highly dispersed ceria on activated carbon for the catalyzed ozonation of organic pollutants, Applied Catalysis B: Environmental, 2012, 113– 114: 308– 317.
    [23] Anaid CQ, Carlos BD, Gabriela R, Patricia BH, Rubí R, and Reyna N, Wastewater ozonation catalyzed by iron, Industrial &Engineering Chemical Research, 2011, 50: 2488-2494.
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HE Hongping, WU Deli, MA Luming, LV Yaping. Ozonation of Aqueous Reactive Black 5 Catalyzed by Modified PyC[J].同济大学学报(自然科学版),2015,43(11):1728~1734

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History
  • Received:October 23,2014
  • Revised:July 31,2015
  • Adopted:March 18,2015
  • Online: November 16,2015
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