Comparison of Degradation Efficiency of Multiple Emerging Pollutants in Source Water by Different Pre-oxidation Processes
CSTR:
Author:
Affiliation:

1.College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China;2.Shanghai National Engineering Research Center of Urban Water Resources Co. Ltd., Shanghai 200082, China

Clc Number:

X 524

  • Article
  • | |
  • Metrics
  • |
  • Reference [35]
  • |
  • Related [20]
  • | | |
  • Comments
    Abstract:

    Taking raw water from a water source in Shanghai as the research object, the effects of different pre-oxidation processes on the removal of characteristic pollutants were studied for the characteristic pollutants such as antibiotics and pesticides present in the source water. This study found that the ability of the removal of antibiotics under the same dose (0.2 ~ 0.8 mg·L-1) of oxidant is ozone > potassium permanganate > free chlorine; the more dosage of each oxidant, the higher the removal rate of antibiotics. The ability of potassium permanganate to remove antibiotics first rises and then falls with pH increasing, while free chlorine and ozone gradually increases. The ability of removal of organic chlorine pesticides under the same dose oxidant is ozone > potassium permanganate > free chlorine. With the increase of pH, the removal ability of potassium permanganate to organic chlorine pesticides decreases, and the ability to remove ozone increases. The removal ability of free chlorine unchanged.

    Reference
    [1] 陆纳新,袁君,高乃云,等. 不同预氧化剂和臭氧-生物活性炭工艺对水中有机物和氨氮的去除效果[J]. 净水技术, 2014,33(S2): 98.
    [2] 李秋霞,孙洪伟,赖能城,等. 预氯化去除饮用水水源中高浓度氨氮等污染因子的应急处理研究[J]. 水处理技术, 2010, 36(3): 99.
    [3] 万晓辉. 高锰酸钾氧化氟喹诺酮类抗生素的动力学和反应历程研究 [D]. 哈尔滨:哈尔滨工业大学,2012.
    [4] LANGE F, CORNELISSEN S, KUBAC D,et al. Degradation of macrolide antibiotics by ozone: a mechanistic case study with clarithromycin[J]. Chemosphere,2006,65(1): 17.
    [5] De WITTE B , DEWULF J, DEMEESTERE K,et al., Ozonation and advanced oxidation by the peroxone process of ciprofloxacin in water[J].Journal of Hazardous Materials,2008,161(2): 701.
    [6] DANTAS R F, CONTRERAS S, SANS C,et al. Sulfamethoxazole abatement by means of ozonation[J]. Journal of Hazardous Materials,2008,150(3): 790.
    [7] JARVIE M E,HAND D W,BHUVENDRALINGAM S,et al. Simulating the performance of fixed-bed granular activated carbon adsorbers: Removal of synthetic organic chemicals in the presence of background organic matter[J]. Water Research,2005,39(11): 2407.
    [8] 张涛,郭晓,刘俊杰,等. 江西梅江流域土壤中四环素类抗生素的含量及空间分布特征[J]. 环境科学学报, 2017. 37(4): 1493.
    [9] 张明,花日茂,李学德,等. 巢湖表层水体中有机氯农药的分布及其组成[J]. 应用生态学报, 2010, 21(1): 209.
    [10] 雷昌文,曹莹,周腾耀,等. 太湖水体中5种有机磷农药混合物生态风险评价[J]. 生态毒理学报, 2013, 8(6): 937.
    [11] 孙秋根,王智源,董建玮,等.太湖流域河网4种典型抗生素的时空分布和风险评价[J]. 环境科学学报, 2018,38(11): 4400.
    [12] NA T W, KANG T W, LEE K H, et al. Distribution and ecological risk of pharmaceuticals in surface water of the Yeongsan river, Republic of Korea[J]. Ecotoxicology and Environmental Safety. Academic Press,2019,181: 180.
    [13] LIN Tian, HU Zhaohui, ZHANG Gan,et al. Levels and mass burden of DDTs in sediments from fishing harbors: the importance of DDT-containing antifouling paint to the coastal environment of China.[J]. Environmental Science & Technology,2009,43(21): 8033.
    [14] WANG Jun, GUO Lingli, LI Jun,et al., Passive air sampling of DDT, chlordane and HCB in the Pearl River Delta, South China : implications to regional sources.[J]. Journal of Environmental Monitoring : 2007,9(6): 582.
    [15] YU Huanyun, BAO Lianjun, LIANG Yan,et al. Field validation of anaerobic degradation pathways for dichlorodiphenyltrichloroethane (DDT) and 13 metabolites in marine sediment cores from China.[J]. Environmental Science & Technology,2011,45(12): 5245.
    [16] LI F B , LI X M , GU ZHO S,et al., Enhanced reductive dechlorination of DDT in an anaerobic system of dissimilatory iron-reducing bacteria and iron oxide[J]. Environmental Pollution,2009,158(5):1733.
    [17] LARSON S J, CAPEL P D, MAJEWSKI M. Pesticides in surface waters: distribution, trends, and governing factors[M]. [S.l]:CRC Press,1997.
    [18] STACKELBERG Paul E, FURLONG Edward T, MEYER Michael T,et al. Persistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant[J]. Science of the Total Environment,2004,329(1): 99.
    [19] FATIMA T, FABIEN M, BARBARA L B,et al. Occurrence and fate of antibiotics in the Seine River in various hydrological conditions[J]. The Science of the Total Environment, 2008, 393(1): 84.
    [20] WATKINSON A J, MURBY E J, KOLPIN DW,et al. The occurrence of antibiotics in an urban watershed: from wastewater to drinking water[J]. Science of the Total Environment,2008,407(8): 2711.
    [21] TANG Jun, SHI Taozhong, WU Xiangwei,et al. The occurrence and distribution of antibiotics in Lake Chaohu, China: Seasonal variation, potential source and risk assessment[J]. Chemosphere,2015,122(mar): 154.
    [22] JIANG Lei, HU Xialin, YIN Daqiang,et al. Occurrence, distribution and seasonal variation of antibiotics in the Huangpu River, Shanghai, China.[J]. Chemosphere,2011,82(6): 822.
    [23] ALEXEEVA L B, STRACHAN W M J, SHLYCHKOVA V V,et al. Organochlorine pesticide and trace metal monitoring of russian rivers flowing to the arctic ocean: 1990—1996[J]. Marine Pollution Bulletin,2001,43(1/6): 71.
    [24] SINGH K. P., MALIK A., MOHAN D. et al., Distribution of persistent organochlorine pesticide residues in Gomti River, India[J]. Bulletin of Environmental Contamination and Toxicology,2005,74(1): 146.
    [25] GOLFINOPOULOS S K, NIKOLAOU A D, KOSTOPOULOU M N,et al. Organochlorine pesticides in the surface waters of Northern Greece[J]. Chemosphere,2003,50(4): 507.
    [26] 于英鹏,刘敏. 太湖流域水源地有机氯农药分布特征与生态风险评价[J]. 环境污染与防治, 2017. 39(8): 829.
    [27] 刘翠翠,何洁妮,仇雁翎,等.黄浦江水相中有机氯农药的污染特征分析[J].环境化学,2017,36(4):849.
    [28] ACERO J L , RODRIGUEZ E , MERILUOTO J. Kinetics of reactions between chlorine and the cyanobacterial toxins microcystins[J]. Water Research, 2005,39(8): 1628.
    [29] 林巍. 常用预氧化剂降解两种典型PPCPs的效能和机理研究[D].哈尔滨:哈尔滨工业大学,2013.
    [30] LI Yuhu, LI Ping, MA Wandong,et al. Spatial and temporal distribution and risk assessment of polycyclic aromatic hydrocarbons in surface seawater from the Haikou Bay, China[J]. Marine Pollution Bulletin,2015,92(1/2): 244.
    [31] 吴永强. 饮用水水源突发有机氯农药污染的应急处理研究[D].哈尔滨:哈尔滨工业大学,2011.
    [32] 杨威.水合二氧化锰去除水源水中有机污染物的初步实验研究[J]. 化学与黏合, 2008(4): 17.
    [33] 刘锐平,杨艳玲,李圭白,等.腐殖酸在水合二氧化锰表面的吸附行为[J]. 环境科学学报, 2005(3): 351.
    [34] LI Bing, ZHANG Tong. pH significantly affects removal of trace antibiotics in chlorination of municipal wastewater[J]. Water Research,2012,46(11): 3703.
    [35] WANG P, HE Y,HUANG C. Reactions of tetracycline antibiotics with chlorine dioxide and free chlorine[J]. Water Research, 2011. 45(4): 1838.
    Cited by
    Comments
    Comments
    分享到微博
    Submit
Get Citation

XU Bin, AI Jian, QIAN Hao, TANG Yulin. Comparison of Degradation Efficiency of Multiple Emerging Pollutants in Source Water by Different Pre-oxidation Processes[J].同济大学学报(自然科学版),2021,49(9):1234~1242

Copy
Share
Article Metrics
  • Abstract:347
  • PDF: 1199
  • HTML: 477
  • Cited by: 0
History
  • Received:June 07,2021
  • Online: September 27,2021
Article QR Code